Unpicking vibration-vibration and vibration-torsion interactions in m-fluorotoluene
نویسندگان
چکیده
Two-dimensional laser-induced fluorescence (2D-LIF) spectra are reported for a set of features in the S1 ↔ S0 electronic spectrum m-fluorotoluene. Two transitions previously assigned to fundamentals reassigned present work. The main reassignments confirmed with zero-electron-kinetic-energy (ZEKE) spectroscopy. Interactions S0, and D0+ states involving vibrational vibration-torsional (“vibtor”) levels identified via observed activity. obtained wavenumbers compare well results quantum chemical calculations.
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ژورنال
عنوان ژورنال: Journal of Molecular Spectroscopy
سال: 2021
ISSN: ['0022-2852', '1096-083X']
DOI: https://doi.org/10.1016/j.jms.2021.111522